摘要
Themulti-photonionizationspectrumofNOinthewavelengthregionof575-680nmisobtainedwithanopticalparametergeneratorandamplifier(OPG/OPA)pumpedbyapicosecondNd:YAGlaserasradiationsource.ThebandedstructureofthespectrumindicatesthatNOmoleculeisionizedinresonantmannerandthepeaksofthespectrumareassignedtothetransitionofNOmoleculefromthegroundelectronicstatetoA2∑(v'=0,1,2,3),E2∑(v'=0,1,2),F2Δ(v'=0,1,2,3)andH2∑(v'=0,1,2)intermediateresonantones.ThemoleculeconstantsaboutNO(A2∑,E2∑,F2Δ,H2∑)statesarecalculatedfromthecenterwavelengthofthespectrum.ItisalsofoundthatowingtothespecialelectronconfigurationofNO,thismoleculedoesnotfollowthenormaltransitionselectionruleofthediatomicmoleculeduringthemulti-photonprocess.
出版日期
2006年08月18日(中国Betway体育网页登陆平台首次上网日期,不代表论文的发表时间)