Synthesis,Structure and Characterization of Two—dimensional Network Copper Complex [Cu3（nta）2（azpy）2（H2O）2]·6H2O-中国Betway体育网页登陆

摘要 Thecopper(Ⅱ）complex[Cu3(nta)2(azpy)2(H2O2)]·6H2O(nta=nitrilotriacetate,azpy=4,4′-azobispyridine)hasbeensynthesizedandcharacterized.TheX-rayanalysisrevealsthattherearetwokindsofcopper(Ⅱ）coordinationenvironments.Cu(1)hasadistortedsquareplanesymmetryandCu(2)hasadistortedoctahedralsymmetry.Cu(1)islinkedtoCu(2)throughntaandboundtoCu(1C)byazpy,andCu(2)islinkedtoCu(2A)throughazpy,whichextendstotwo-dimensionalnetworkwithlargerhombus1.2nm×1.7nm.

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Synthesis,Structure and Characterization of Two—dimensional Network Copper Complex [Cu3（nta）2（azpy）2（H2O）2]·6H2O

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