摘要
Unlikeorganic–inorganichybridperovskites,all-inorganiccesiumleadhalideperovskitesholdgreatpromisefordevelopinghigh-performanceoptoelectronicdevices,owingtotheirimprovedstability.Herein,weinvestigatetheperovskite-relatedCsPb2Br5nanoplatelets(NPLs)withtunableemissionwavelengthsviachangingthereactiontemperaturesto100°C,120°C,and140°C.ReactiontemperatureplaysakeyroleindeterminingtheshapesandthicknessesoftheresultingCsPb2Br5NPLs.AhighertemperatureisinfavoroftheformationofsmallerandthickerNPLs.Todeveloptheirpotentialapplicationsinoptoelectronicdevices,greenlightemittingdiodes(LEDs)andphotodetectorsbasedonCsPb2Br5NPLsarefabricated.ThegreenLEDsbasedonCsPb2Br5NPLssynthesizedat140°Cexhibitanexcellentpuregreenemission(fullwidthathalf-maximumof<20nm)anddisplayaluminousefficiencyof34.49lm∕Wunderanoperationcurrentof10mA.Moreover,thephotodetectorbasedonCsPb2Br5NPLssynthesizedat100°Chasbetterperformancewitharisetimeof0.426s,adecaytimeof0.422s,andaratioofthecurrent(withandwithoutirradiation)of364%.
出版日期
2017年05月15日(中国Betway体育网页登陆平台首次上网日期,不代表论文的发表时间)