Preparation of Li[Ni1/3Co1/3Mn1/3]O2 powders for cathode material in secondary battery by solid-state method-中国Betway体育网页登陆

摘要 EmployingLi2CO3,NiO,Co3O4,andMnCO3powdersasstartingmaterials,Li[Ni1/3Co1/3Mn1/3]O2wassynthesizedbysolid-statereactionmethod.Variousgrindingaidswereappliedduringmillinginordertooptimizethesynthesisprocess.Aftersuccessiveheattreatmentsat650and950℃,thepreparedpowderswerecharacterizedbyX-raydiffraction(XRD)analysis,scanningelectronmicroscopy,andtransmissionelectronmicroscopy.Thepowderspreparedbyaddingsalt(NaCl)asgrindingaidexhibitaclearR3mlayerstructure.ThepowdersbyothergrindingaidslikeheptaneshowsomeimpuritypeaksintheXRDpattern.Theformerpowdersshowauniformparticlesizedistributionoflessthan1μmaveragesizewhilethelattershowsawidedistributionrangingfrom1to10μm.EnergydispersiveX-ray(EDX)analysissshowthattheratioofNi,Co,andMncontentinthepowderisapproximately1/3,1/3,and1/3,respecively.TheEDXdataindicatenoincorporationofsodiumorchlorineintothepowders.Charge-dischargetestsgaveaninitialdischargecapacityof160mAh·g-1forthepowderswithNaCladditionwhile70mAh·g-1forthepowderswithheptane.

1Yingfang ZHU;Jingwei YOU;Haifu HUANG;Guangxu LI;Wenzheng ZHOU;Jin GUO.Facile synthesis and electrochemical properties of layered Li[Ni1/3Mn1/3Co1/3]O2 as cathode materials for lithium-ion batteries.材料科学与工程,2017-02.
2殷康健;赵瑞瑞;朱继涛;蒋建辉;陈红雨.碳包覆对LiNi1/3Co1/3Mn1/3O2正极材料性能影响.电力电子与电力传动,2014-03.
3WANG Zhenjie;DU Junlin;LI Zhilin;WU Zhu.Influence of Sintering Temperature on the Structure and High-temperature Discharge Performance of Li Ni_（1/3）Mn_（1/3）Co_（1/3）O_2 Cathode Materials.材料科学与工程,2015-05.
4LI Zhigang WANG Tiandiao KANG Xueya.Synthesis and characterization of LiCo1/3Ni1/3Mn1/3O2 prepared by Pechini process.金属材料,2006-06.
5陈添才;王剑华;刘浪;顾琳.Li（Ni（1/3）Co（1/3）Mn（1/3））（1-x）ZnxO2固溶体的XRD及XPS研究.电力电子与电力传动,2009-05.
6龚蓉;陈红雨.三元正极材料LiMn1/3Ni1/3Co1/3O2改性研究现状.电力电子与电力传动,2014-01.
7肖芬.喷雾干燥法合成(LiFe1/3Mn1/3Co1/3PO4/C及其电化学性能.电力电子与电力传动,2016-01.
8卢丽莎;韩恩山;朱令之.LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2的合成及其过充电性能.电力电子与电力传动,2012-02.
9Jianfei Yu;Lin Zhu;Cheng Fan;Cheng Zan;Ling Hu;Shuhui Yang;Qiang Zhang;Wancheng Zhu;Lin Shi;Fei Wei.Highly dispersed Mn2O3 microspheres： Facile solvothermal synthesis and their application as Li-ion battery anodes.力学,2015-05.
10刘华亭;陈汝芬;宋秀芹.Preparation of Li4.4Al0.4Si0.6O4-xLi3BO3 Solid Electrolytes by Sol-Gel Method and Their Ionic Conductivity.化学,2002-12.

Preparation of Li[Ni1/3Co1/3Mn1/3]O2 powders for cathode material in secondary battery by solid-state method

来源期刊

相关推荐

同分类资源更多

相关关键词