EFFECT OF MOLECULAR WEIGHT OF PEO ON THE STRUCTURE AND PROPERTIES OF PDMAEMA/PEO HYDROGELS

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    摘要 Anewkindofbinaryhydrogelscomposedofpoly(dimethylaminoethylmethacrylate)(PDMAEMA)andpoly(ethyleneoxide)(PEO)withvaryingweightaveragemolecularweights((?)_w=5×10~4,1×10~5and2.5×10~6)werepreparedbyγ-irradiationtechnology.ThepropertiesofPDMAEMA/PEOhydrogelsobtainedwereevaluatedintermsofgelfraction,gelstrength,thermalcharacterizationandswellingbehavior.ThegelstrengthandswellingdegreeofthehydrogelscouldbeimprovedobviouslyafteraddingPEOintothePDMAEMAsystem,whilethedegreeofimprovementdecreasedwithincreasing(?)_wofPEO.ThetemperaturesensitivityofPDMAEMA/PEOwasretainedonlyinthesamplewithPEOof(?)_w=5×10~4,andthepHsensitivitywasretainedinsampleswithPEOof(?)_w=5×10~4and1×10~5.WhenDMAEMA/PEOmixturescontainingPEOof(?)_w=5×10~4wereirradiated,themainreactioncouldbethecross-linkingofDMAEMA,andthelinearPEOmolecularchainscouldpenetrateintothecross-linkednetworkofPDMAEMA.Withincreasing(?)_wofPEO,somesidereactionswereinduced,suchasgraftingofDMAEMAontoPEOmolecules,thescissionorcross-linkingofPEO.
    机构地区 不详
    出版日期 2006年01月11日(中国Betway体育网页登陆平台首次上网日期,不代表论文的发表时间)
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