摘要
Theadsorptionbehaviorsandmechanismofanovelchelateresin,macroporousphosphonicacidresin(PAR)forGd(Ⅲ)wereinvestigated.Thestaticallyanddynamicallysaturatedadsorptioncapacityisrespectively308mg·g-1resinand296mg·g-1resinat298KinHac-NaAcmediumatpH5.6.Gd(Ⅲ)adsorbedonPARcanbereductivelyelutedby0.5～5.0mol·L-1HClusedaseluantandtheelutionpercentageisupto94.7%in1.0mol·L-1HCl.Theresincanberegeneratedandreusedwithoutapparentdecreaseinadsorptioncapacity.Theapparentadsorptionrateconstantisk298=3.96×10-5s-1.TheadsorptionbehaviorofPARforGd(Ⅲ)conformstotheFreundlichisotherm.Thethermodynamicadsorptionparameter,enthalpychange△HofPARforGd(Ⅲ)is22.6kJ·mol-1.Theapparentadsorptionactivationenergy(Ea)ofPARforGd(Ⅲ)is5.0kJ·mol-1.ThemolarcoordinationratioofthefunctionalgroupofPARtoGd(Ⅲ)isabout3∶1.TheadsorptionmechanismofPARforGd(Ⅲ)wasexaminedbyusingchemicalmethodandIRspectrometry.
出版日期
2004年06月16日（中国Betway体育网页登陆平台首次上网日期，不代表论文的发表时间）
