Annealing temperature dependent catalytic water oxidation activity of iron oxyhydroxide thin films

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摘要 Nanostructuredironoxyhydroxide(FeOOH)thinfilmshavebeensynthesizedusinganelectrodepositionmethodonanickelfoam(NF)substrateandeffectofairannealingtemperatureonthecatalyticperformanceisstudied.Theas-depositedandannealedthinfilmswerecharacterizedbyX-raydiffraction(XRD),X-rayphotoelectronspectroscopy(XPS),fieldemissionscanningelectronmicroscopy(FE-SEM)andlinearsweepvoltammetry(LSV)todeterminetheirstructural,morphological,compositionalandelectrochemicalproperties,respectively.Theas-depositednanostructuredamorphousFeOOHthinfilmisconvertedintoapolycrystallineFe2O3withhematitecrystalstructureatahightemperature.TheFeOOHthinfilmactsasanefficientelectrocatalystfortheoxygenevolutionreaction(OER)inanalkaline1MKOHelectrolyte.Thefilmannealedat200°Cshowshighcatalyticactivitywithanonsetoverpotentialof240mVwithasmallerTafelslopeof48mV/dec.Additionally,itneedsanoverpotentialof290mVtothedrivethecurrentdensityof10mA/cm2andshowsgoodstabilityinthe1MKOHelectrolytesolution.
机构地区 不详
出处 《能源化学:英文版》 2017年4期
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出版日期 2017年04月14日(中国Betway体育网页登陆平台首次上网日期,不代表论文的发表时间)
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