摘要
Flowbatterieswithhighenergydensityandlongcyclelifehavebeenpursuedtoadvancetheprogressofenergystorageandgridapplication.Non-aqueousbatterieswithwidevoltagewindowsrepresentapromisingtechnologywithoutthelimitationofwaterelectrolysis,buttheysufferfromlowelectrolyteconcentrationandunsatisfactorybatteryperformance.Here,anon-aqueouslithiumbrominerechargeablebatteryisproposed,whichisbasedonBr2/Br-andLi+/Liasactiveredoxpairs,withfastredoxkineticsandgoodstability.TheLi/Brbatterycombinestheadvantagesofhighoutputvoltage(3.1V),electrolyteconcentration(3.0mol/L),maximumpowerdensity(29.1mW/cm2)andpracticalenergydensity(232.6Wh/kg).Additionally,thebatterydisplaysacolumbicefficiency(CE)of90.0%,avoltageefficiency(VE)of88.0%andanenergyefficiency(EE)of80.0%at1.0mA/cm2aftercontinuouslyrunningformorethan1000cycles,whichisbyfarthelongestcyclelifereportedfornon-aqueousflowbatteries.
出版日期
2017年04月14日(中国Betway体育网页登陆平台首次上网日期,不代表论文的发表时间)