Creating mesopores in ZSM-48 zeolite by alkali treatment: Enhanced catalyst for hydroisomerization of hexadecane-中国Betway体育网页登陆

摘要 ZSM-48zeoliteswithvariousSi/AlratioswerehydrothermallysynthesizedintheH2N（CH2）6NH2（HDA）-containingmedia.TheobtainedsampleswerehighlycrystallizedwithminormixedphasesasevidencedbyX-raypowderdiffraction（XRD）.ThealkalinetreatedZSM-48zeolitesmaintaineditsstructureunderdifferentconcentrationsofNaOHaqueoussolution.Microporesremainedunchangedwhilemesoporeswithwideporesizedistributionformedafterthealkalinetreatment.Thesurfaceareaincreasedfrom228to288m2/g.TheBr?nstedacidsiteshadlittlealterationwhileanobviousincreaseofLewisacidsiteswasobserved.Thehydroisomerizationofhexadecanewasperformedasthemodelreactiontotesttheeffectsofthealkalitreatment.Theconversionofhexadecanehadalmostnochange,whichwasattributedtothepreservationoftheBr?nstedacidsites.Whilehighselectivitytoiso-hexadecanewithanimprovedisotonormalratioofalkaneswasduetothemesoporeformationandimproveddiffusivity.

1Tingjun Fu;Jiangwei Chang;Juan Shao;Zhong Li.Fabrication of a nano-sized ZSM-5 zeolite with intercrystalline mesopores for conversion of methanol to gasoline.物理,2017-01.
2Jiang Binbo;Zhou Bingjie;Yan Lixia;Wei Lingze;Xu Caixia;Liao Zuwei;Huang Zhengliang;Wang Jingdai;Yang Yongrong.Effect of Hydrothermal Treatment on Suppressing Coking of ZSM-5 Zeolite during Methanol-to-Propylene Reaction.油气加工工程,2016-02.
3Hongyu Wu;Min Liu;Wei Tan;Keke Hou;Anfeng Zhang;Yiren Wang;Xinwen Guo.Effect of ZSM-5 zeolite morphology on the catalytic performance of the alkylation of toluene with methanol.物理,2014-04.
4Hui Luo;Xiao-Dong Wu;Duan Weng;Shuang Liu;Rui Ran.A novel insight into enhanced propane combustion performance onPtUSY catalyst.金属材料,2017-01.
5郑坚;董家禄;须沁华;胡澄.Study on Pt/KL Zeolite Catalyst for n-Hexane Aromatization Modified by Lanthanum.有色金属冶金,1999-04.
6M. Marigo;D.L. Cairns;J. Bowen;A. Ingram;E.H. Stitt.Relationship between single and bulk mechanical properties for zeolite ZSM5 spray-dried particles.力学,2014-03.
7Santosh S.Katkar;Pravinkumar H.Mohite;Lakshman S.Gadekar;Kaluram N.Vidhate;Machhindra K.Lande.ZnO-beta zeolite:As an effective and eco-friendly heterogeneous catalyst for the synthesis of benzothiazole derivatives.化学,2010-04.
8WANG RongMin.Preparation of Molecular Sieve Catalyst and Application in the Catalytic Oxidation Treatment of Waste Water.化学,2001-12.
9Junjie Li;Min Liu;Xinwen Guo;Chengyi Dai;Chunshan Song.Fluoride-mediated nano-sized high-silica ZSM-5 as an ultrastable catalyst for methanol conversion to propylene.物理,2018-04.
10.The Project “Research and Development of Monocrystalline Multi-interstitial HTS-3 Zeolite Catalyst” Passed Technical Appraisal of Sinopec Corp.油气加工工程,2014-02.

Creating mesopores in ZSM-48 zeolite by alkali treatment: Enhanced catalyst for hydroisomerization of hexadecane

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