One—dimensional Network Constructed by Salicylate and Phenanthroline Ligands with Copper(Ⅱ)

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    摘要 Anovelcomplex,[Cu2(phen)(sal)(Hsal)2]n(1),wassynthesizedandstructurallycharacterized.Thebasicdimericunitsareholdbysalligandsandextendedinto1-Dnetwork.Thecarboxylategrougsofsalicylatescoordinatetothecentralioninthreedifferentcoordinationmodes:chelating,bridgingandbridging-chelating.Inthecaseofbridging-chelatingofthecarboxylategroupofthesalicylate,allthreeoxygenatomsofsalicylatearebidentatelycoordinatedtocopperion,namely,μ4-η^3bindingmode.
    机构地区 不详
    出处 《中国化学:英文版》 2002年10期
    出版日期 2002年10月20日(中国Betway体育网页登陆平台首次上网日期,不代表论文的发表时间)
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