摘要
Anovelcomplex,[Cu2(phen)(sal)(Hsal)2]n(1),wassynthesizedandstructurallycharacterized.Thebasicdimericunitsareholdbysalligandsandextendedinto1-Dnetwork.Thecarboxylategrougsofsalicylatescoordinatetothecentralioninthreedifferentcoordinationmodes:chelating,bridgingandbridging-chelating.Inthecaseofbridging-chelatingofthecarboxylategroupofthesalicylate,allthreeoxygenatomsofsalicylatearebidentatelycoordinatedtocopperion,namely,μ4-η^3bindingmode.
出版日期
2002年10月20日(中国Betway体育网页登陆平台首次上网日期,不代表论文的发表时间)