Required catalytic properties for alkane production from carboxylic acids: Hydrodeoxygenation of acetic acid-中国Betway体育网页登陆

摘要 ThesupportedPtcatalysts(1wt%)werepreparedbytheincipientimpregnationmethodandanalyzedusingsynchrotron-basedX-raydiffraction,BETsurfacearea,oxygenadsorption,COpulsechemisorption,temperature-programmeddesorption(TPD)ofaceticacid,H2-TPD,NH3-TPD,O2-TPD,andH2-TPR.ThereactivityofPt-basedcatalystswasstudiedusingafixedbedreactorat300Cand4MPaforhydrodeoxygenationofaceticacid,wherePt/TiO2wasveryselectiveforethaneproduction.TPDexperimentsrevealedthatseveralconditionsmustbesatisfiedtoachievethishighselectivitytoethanefromaceticacid,suchasPtsites,moderateacidity,andmediummetal-oxygenbondstrengthintheoxidesupport.Thisworkprovidesinsightsindevelopingnovelcatalyticmaterialsforhydrocarbonproductionsfromvariousorganicsincludingbio-fuels.

1PANBingcai CHENJinlong 等.TREATMENT AND RESOURSE REUSE OF INDUSTRIAL WASTEWATER FROM PRODUCTION PROCESS OF PHENYL ACETIC ACID.高分子化学,1999-01.
2YuShanxin ZHAOZongbao 等.CATALYTIC ESTERIFICATION OF CARBOXYLIC ACIDS WITH ALCOHOLS BY SULFO—POLYVINYL CHLORIDE.高分子化学,1993-02.
3.Nanjing to Construct the Largest in China Acetic Acid Production Base.油气加工工程,2007-03.
4Guo, Yuan;Lu, Zhenhuan;Yao, Libo;Shi, Zhen.A Novel Synthetic Method for the Preparation of Aliphatic Aldehydes from the Corresponding Carboxylic Acids.化学,2011-03.
5HuangWenqiang HouXin 等.SYNTESIS OF THE COMPLEXES OF MACROPOROUS SULFONATED RESINS WITH FERRIC CHLORIDE AND THEIR CATALYTIC BEHAVIOR FOR SETERIFICATION OF ACETIC ACID WITH BUTANOL.高分子化学,1997-01.
6FENGWenguo;SUXing;等.TREATMENT OF WASTEWATER FROM PRODUCTION PROCESS OF 2，3—ACID.高分子化学,1999-01.
7Ma Ruixia;Wang Ruifen;Wang Shuping;Zhang Jianjun.Synthesis and Properties of Ternary Europium Complexes with Aromatic Carboxylic Acid and ,Nitrogen-Containing Heterocyclic Ligand.有色金属冶金,2006-03.
8.Wood Properties of Poplar from Stand Affected by Acid Rain.林学,2002-03.
9Menghe Miao.Yarn spun from carbon nanotube forests Production, structure, properties and applications.力学,2013-04.
10Zhong He;Xianqin Wang.Intrinsic properties of active sites for hydrogen production from alcohols without coke formation.物理,2013-03.

Required catalytic properties for alkane production from carboxylic acids: Hydrodeoxygenation of acetic acid

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