Synthesis and Crystal Structure of a Novel Ion-pair Complex of [Li（THF）4Nd（C8H8）2]·2THF-中国Betway体育网页登陆

摘要 ThereactionofNdCl3withlithiummethylnaphthalenein1:2moleratioinTHFgeneratesblackpowder.Thepowderreactswithcyclooctatetraene（COT）inTHFtoformthetitlecomplex.[Li（THF）4Nd（C8H8）2]·2THFcrystallizesinthemonoclinicspacegroupP2/cwithunit-celldimensionsa=1.7858（7）nm,h=1.3243（4）nm,c=1.8086（6）nm.β=106.52（4）°,V=4.10nm3andDc=1.268g/cm3forZ=4.F（000）=1660,R=0.0774,Rn=0.0733.Thecomplexconsistsofdiscreteion-pairandtwoTHFmoleculesadduct.Intheanion,theneodymiumatomiscoordinatedbytwoCOTrings.ThestructureofthecationshowsthatthelithiumatomisattachedwithTHFmoleculesonly.

1.Syntheses of（C8H8）Ln（C9H7）·（THF）2（Ln=Pr,Nd）and crystal structure of（C8H8）Pr（C9H7）·（THF）2.化学,1992-04.
2LI, Hong-Xi;ZHANG, Yong;REN, Zhi-Gang;CHENG, Mei-Ling;WANG, Jing;LANG, Jian-Ping.Synthesis of Novel Binuclear Samarium Thiolate Complexes [（THF）3I2Sm（μ-SAr）]2 （Ar=Ph, 4-Me2NC6H4） and Crystal Structure of [（THF）3I2Sm（μ-S-4-Me2NC6H4）]2.化学,2005-11.
3何水样;杨锐;武望婷;史启祯;王大奇;安德荣.Crystal Structure and Bioactivity of Complex [Gd（C10H9N2O4）（C10H8N2O4）（H2O）3]2·phen·4H2O.化学,2005-09.
4MAOHong-yan;LIUHong-lei;ZHANGHong-yun;XUChen;WANGEn-bo;HANHua-yun;WUQing-an;ZHUYu.A Novel Layered Complex with Rhomboidal Channels： Hydrothermal Synthesis, Crystal Structure, and Properties of Cu （4,4′-bipy）2（H2PO4）2（H2O）2（bipy=bipyridine）.化学,2004-03.
5YU Li LIU Jiang-ping WANG Jing-ping NIU Jing-yang.Hydrothermal Synthesis and Crystal Structure of a New 2D Layer Compound [{Ni（en）2}2Sb8V14O42]·5.5H2O.化学,2009-04.
6WANG，Da－Qi;YU，Qing－Jiang;等.Two—dimensional Network Crown Ether Complex.Synthesis and Crystal Structure of 18—Crown—6 Complex：[K（18—C—6）]2[Cd—（nmt）2].化学,2002-02.
7石恒真;单永奎;何鸣元;刘煜炎;翁林红.Synthesis and Structure of the First Protonated Zincoborophosphate：（ H3O ） Zn（ H2O ） 2BP2O8·H2O.化学,2003-09.
8.Polymerization of Phenyl Isocyanate by Divalent Samarium Complex （ArO）2Sm（THF）4 （ArO=2,6-di-tert-butyl-4-methylphenoxo）.化学,1997-07.
9刘盛华;谌了容;付恩琴;吴成泰.Synthesis and crystal structure of dinuclear nickel (Ⅱ) complex.化学,1999-01.
10乐学义;童明良;等.A Novel Cu(Ⅱ） Complex with 2,2′-Bipyridyl and L-Methioninate -synthesis,Characterization,Molecular Structure and Stability.化学,2003-01.

Synthesis and Crystal Structure of a Novel Ion-pair Complex of [Li（THF）4Nd（C8H8）2]·2THF

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