Synthesis and crystal structure of [Co（mpt）2{P（OCH3）3}2]BF4 （Hmpt = 2-mercaptothiazoline）-中国Betway体育网页登陆

摘要 Themonomericcobalt-phosphite-thiolatocomplex[Co(mpt)2{P(OCH3)3}2]BF4(Hmpt=2-mercaptothiazoline)hasbeenpreparedandcharacterizedbyX-raycrystallography.ThecomplexcrystallizesinthemonoclinicspacegroupC2/cwitha=0.8078(5),b=2.6020(18),c=1.2191(7)nm,β=99.38(1)°,V=2.528(3)nm3,andZ=4.Thestructurecomprisesdiscretecations[Co(mpt)2{P(OCH3)3}2.]+andanionsBF4-,inwhichthecobalt(Ⅲ)atomiscoordinatedtotwochelatempt-andtwoas-orientedmonodentateP(OCH3)3ligandsinahighlydistortedoctahedralgeometry.ThemostdistortedanglesareS(2)-Co(1)-S(2a)of162.23(10)°andN(1)-Co(1)-S(2)of71.47(13)°,thelatteriscausedbythegeometricconstraintofthebidentateligandmpt-.CyclicvoltammetryhasbeenusedtostudytheelectrochemicalbehaviorofthetitlecomplexontheRelectrodeinMeCNsolutionwith0.1mol·L-1ofBun4NBF4aselectrolyte.TheresultsindicatethatthetitlecomplexisunstableinMeCN.

1.CRYSTAL AND MOLECULAR STRUCTURE OF THE ADDUCT OF Ni（TAAB）（BF4）2WITH PYRIDINE.化学,1992-09.
2何晓康;刘建鹏;张祥;沈咏;邹宏新.Forbidden transition properties of fine-structure 2p3 4S3/2-2p3 2Da/2,s/2 for nitrogen-like ions.物理,2018-08.
3乔善宝;焦昌梅;张文华;任志刚;张勇;郎建平.Synthesis and Crystal Structure of a 2D Honeycomb-like Polymeric Cluster （Et4N）3{[MoS4Cu2（μ-CN）]2（μ＇-CN）}·2MeCN.化学,2005-08.
4LI, Hong-Xi;ZHANG, Yong;REN, Zhi-Gang;CHENG, Mei-Ling;WANG, Jing;LANG, Jian-Ping.Synthesis of Novel Binuclear Samarium Thiolate Complexes [（THF）3I2Sm（μ-SAr）]2 （Ar=Ph, 4-Me2NC6H4） and Crystal Structure of [（THF）3I2Sm（μ-S-4-Me2NC6H4）]2.化学,2005-11.
5邓明宇;周玉芳;姚英明;沈琪;翁林红.Synthesis, Crystal Structure of [ （MeC5H4）2Ln（μ-OCH2 CH2NMe2 ） ]2 （Ln = Sm, Y, Nd） and Their Catalytic Activity for Ring-Opening Polymerization of ε-Caprolactone.有色金属冶金,2003-05.
6.CRYSTAL STRUCTURE OF DI - NITRATOBIS（ETHYLCAPROLACTAM）URANYL（Ⅱ） UO2[CH2（CH2）4CONC2H5]2（NO3）2.化学,1992-03.
7.STUDIES ON RARE EARTH COMPLEXES WITH CROWN ETHERS ⅩⅧ——Synthesis,Characterization and Crystal Structure of[Sc（NO3）3（H2O）2]·（15-Crown-5）.有色金属冶金,1990-01.
8徐抗震;王敏;张航;严彪;宋纪蓉;王伯周;赵凤起.Synthesis, Crystal Structure and Thermal Behavior of 4,5-Diacetoxyl-2-（dinitromethylene）-imidazolidine.化学,2011-11.
9赵聪;朱达川;高唯;韩涛;彭玲玲;涂铭旌.Effect of doping Gd^3＋ on crystal structure and luminescent properties of Sr2SiO4：Eu^2＋ phosphor.有色金属冶金,2015-07.
10MAOHong-yan;LIUHong-lei;ZHANGHong-yun;XUChen;WANGEn-bo;HANHua-yun;WUQing-an;ZHUYu.A Novel Layered Complex with Rhomboidal Channels： Hydrothermal Synthesis, Crystal Structure, and Properties of Cu （4,4′-bipy）2（H2PO4）2（H2O）2（bipy=bipyridine）.化学,2004-03.

Synthesis and crystal structure of [Co（mpt）2{P（OCH3）3}2]BF4 （Hmpt = 2-mercaptothiazoline）

来源期刊

相关推荐

同分类资源更多

相关关键词