摘要
Inthiswork,themorphologiesandporestructuresofaseriesofcorncob-derivedactivatedcarbonsandzeolitetemplatedcarbonwithultrahighsurfaceareawerecarefullyinvestigatedbySEM,HRTEMandN2-sorptioncharacterizationtechnologies.Thehigh-pressurehydrogenuptakeperformancewasanalyzedusingstandardPressure-Composition-Temperatureapparatusinordertostudytheporesizeeffectsonhydrogenuptake.Theseas-obtainedporouscarbonsshoweddifferentcharacteristicsofporesizedistributionaswellasspecificsurfacearea.Theresultsindicatethatthemosteffectiveporesforadsorbinghydrogendependedonthestoragepressure.Theseultramicropores(0.65-0.85nm)couldbethemosteffectiveporesonexcessH2uptakeat1bar,however,micropores(0.85-2nm)wouldplayamoreimportantroleinexcessH2uptakeathigherpressureat77K.Atroomtemperature,poresizeeffectsonH2uptakecapacitywereveryweak.BothspecificsurfaceareaandtotalporevolumeplaymoreimportantrolesthanporesizeforH2uptakeatroomtemperature,whichwasclearlydifferentfromthatat77K.Forapplicationsinfuture,thecorncob-derivedactivatedcarbonscanbemoreavailablethanzeolitetemplatedcarbonsat77K.ElementdopingenhancedhydrogenuptakecouldbemainresearchdirectionforimprovingH2uptakecapacityatroomtemperature.更多还原
出版日期
2015年01月11日（中国Betway体育网页登陆平台首次上网日期，不代表论文的发表时间）
