Preparation of porous polyimide microspheres by thermal degradation of block copolymers-中国Betway体育网页登陆

摘要 Anewpreparationmethodhasbeendevelopedforthermallystableporouspolyimidemicrospheres.Porouspolyimidemicrosphereswerepreparedusingtriblockcopolymersthatconsistedofathermallystablepolyimidederivedfrompyromelliticdianhydride/4,4’-oxydianilineasthecontinuousphaseandathermallylabilepolyetherasthedispersedphase.Spheresofcopolymersweregeneratedinanonaqueousemulsionandthengraduallyheatedtocompletetheimidizationtoformamicrophase-separatedstructure.Subsequently,thermaltreatmentataslightlyreducedpressureremovedthelabileblocksandproducedpores.Undersuitabledecompositionconditions,theporesizeoftheporouspolyimidewasintherangeof200-400nm.

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Preparation of porous polyimide microspheres by thermal degradation of block copolymers

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