摘要
Lithiumsulfurbattery(LSB)offersseveraladvantagessuchasveryhighenergydensity,low-cost,andenvironmental-friendliness.However,itsuffersfromseriousdegradationofitsreversiblecapacitybecauseofthedissolutionofreactionintermediates,lithiumpolysulfides,intotheelectrolyte.Tosolvethislimitation,therearemanystudiesusinggraphene-basedmaterialsduetotheirexcellentmechanicalstrengthandhighconductivity.Comparedwithgraphene,grapheneoxide(GO)containsvariousoxygenfunctionalgroups,whichenhancethereactionwithlithiumpolysulfides.Here,weinvestigatedthepositiveeffectofusingGOmixedwithcarbonblackontheperformanceofcathodeinLSB.WehaveobservedasmallerdropofcapacityinGOmixedsulfurcathode.Wefurtherdemonstratethatthemechanisticoriginofreversibilityimprovement,asconfirmedthroughCVandRamanspectra,canbeexplainedbythestabilizationofsulfurinlithiumpolysulfideintermediatesbyoxygenfunctionalgroupsofGOtopreventdissolution.Ourfindingssuggestthattheuseofgrapheneoxide-basedcathodeisapromisingroutetosignificantlyimprovethereversibilityofcurrentLSB.
出版日期
2013年02月12日(中国Betway体育网页登陆平台首次上网日期,不代表论文的发表时间)