XPS study of tungsten carbide-中国Betway体育网页登陆

摘要 ThesurfacecompositionandelectronicstructureoftungstencarbidespreparedbydirectsynthesisandcarburizationofwhitetungsticacidwerestudiedwithX-rayphotoelectronspectros-copy.TheexperimentalresultsshowthatWO3andfreecarbonarepresentonthesurfaceofthecarbides.Forthehighsurfaceareatungstencarbidepreparedfromwhitetungsticacidalargeextentofoxygeninsertionintothecrystallatticewasobserved.MeasurementsofthebindingenergiesoftheW47/2,C1sandO1scorelevelsindicatethatchargetransferisfromtheWtotheCandOatoms,formingW5d-C2pandW5d-O2pbonding.ThecatalyticbehaviorofthetungstencarbidesinhydrocarbonconversionreactionsismentionedandcomparedwithPtcatalysts.

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XPS study of tungsten carbide

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