PHOTO-AND THERMOSTIMULATED LUMINESCENCE OF BaFCl:Sm CRYSTALS

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    摘要 ThevalencechangesofdopedsamariumandthecreationaswellastheannihilationofF-centersintheprocessesofthermostimulatedluminescence(TSL)andphotostimulatedluminescence(PSL)ofBaFCl∶Smcrystalhavebeenstudied.AsbeingirradiatedbyX-ray,alargenumberofelectron-holepairsarecreatedinthecrystal.Mostoftheelectronsmaybetrappedattheanionvacancies,producingF-centers.Thedopedsamariumions,whichexistedmostlyintrivalentstate(Sm3+),maycapturetheholesandconvertthemselvestotetravalentstate.SothatpartoftheincidentX-rayenergyarestoredinthisnonequilibriumsystem.Onopticalandthermalstimulationthestoredenergycanbeliberatedasacharacteristicemissionoftrivalentsamariumion.ThisemissionoriginatesfromtherecombinationoftheF-centerelectronswithtetravalentsamariumions,i.e.theF-centerelectronsmaybeexcitedtotheconductionbandbyopticalorthermalstirnulationandthenrecombinewithtetravalentsamariumions.ThisrecombinationmakesthesamariumionstobeinsitureducedtotheexcitedstateofSm3+,andgivesrisetothecharacteristicemissionofSm3+.Ontheotherhand,duringX-irradiationafewelectronscanbetrappedatthesitesoftrivalentsamariumionsandreducethemtodivalentstate.ButtheformationofdivalentsamariumOnX-irradiationisverysmallascomparedwiththatofF-centersandsotheirinfluenceonthePSLandTSLcanbeneglected.
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    机构地区 不详
    出版日期 1990年01月11日(中国Betway体育网页登陆平台首次上网日期,不代表论文的发表时间)
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