The structure and magnetic properties of μ3-oxotriiron（Ⅲ） complex [Fe3O（OBz）6（CH3OH）3]（NO3）（CH3OH）2-中国Betway体育网页登陆

摘要 Anewμ3-Otriiron（Ⅲ）complex[Fe3O（OBz）6（CH3OH）3]（NO3）（CH3OH）2（HOBZ=benzoicacid）hasbeensynthesized,itsstructurehasbeendeterminedandvariabletemperaturemagneticsusceptilityhasalsobeenmeasured.Inthemolecule,threeironatomsformedanequilateraltrianglewithu3-Oincenter.ThefittingtothemagneticsusceptibilityshowedthatanintramolecularantiferromagneticexchangeinteractionoccurredbetweenironatomswithJ=-25.51cm-1,andaweakerintermolecularantiferromagneticexchangeinteractionoccurredwithzJ’=-2.30cm-1.

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The structure and magnetic properties of μ3-oxotriiron（Ⅲ） complex [Fe3O（OBz）6（CH3OH）3]（NO3）（CH3OH）2

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